Read: Silver lining for United fan after MK Dons loss
Last season's top four in the English Premiership were all drawn at home while MK Dons are set to face League Two side Bradford City.
The ties for Round three are set to be played during the week starting on September 22.
The draw for the third round of the League Cup:
Chelsea v Bolton Wanderers
Arsenal v Southampton
West Bromwich Albion v Hull City
Crystal Palace v Newcastle United
Leyton Orient v Sheffield United
Cardiff City v AFC Bournemouth
Sunderland v Stoke City
Derby County v Reading
Liverpool v Middlesbrough
Milton Keynes Dons v Bradford City
Manchester City v Sheffield Wednesday
Burton Albion v Brighton and Hove Albion
Swansea City v Everton
Shrewsbury Town v Norwich City
Fulham v Doncaster Rovers
Tottenham Hotspur v Nottingham Forest