Kevin Pietersen will open the batting for the hosts, who have selected an inexperienced bowling lineup Sunday with the 2015 World Cup in mind.
Australia, coming off a 3-0 loss in the Ashes test series, retained the side that beat Scotland in a ODI series warmup on Tuesday.
The first match in the series was washed out Friday without a ball being played at Headingley.
Teams:
England: Michael Carberry, Kevin Pietersen, Jonathan Trott, Joe Root, Eoin Morgan, Ravi Bopara, Jos Buttler, Ben Stokes, James Tredwell, Boyd Rankin, Steven Finn.
Australia: Aaron Finch, Shaun Marsh, Shane Watson, Michael Clarke, George Bailey, Adam Voges, Matthew Wade, James Faulkner, Mitchell Johnson, Clint McKay, Fawad Ahmed.